CHEM 104H Honors General Chemistry

 PROF. GROH

SPRING 2004



Objectives
Professor
Office Hours
Problem Session
Class Meetings
Lab Meetings
Texts and Materials
Grading
Class Format
Assignments
Group Work
The Laboratory
Other Policies
Course Outline
Laboratory Schedule

How To Do Well in CHEM 104H


Links to Various Chemistry/Science Sites

WebElements Periodic Table
Martindale's Virtual Chemistry Center
RasMol and CHIME Molecular visualization freeware
Chemist's Art Gallery: a collection of visualizations and animations  
IBM's STM Image Gallery
"Discover" Magazine
Science News online
Chemical and Engineering News
Scientific American
"Science" magazine
American Scientist
"Nature" magazine
Yahoo! Reuters Science News
Ask Antoine
Marsden's Chem Resources
NIST Chemistry WebBook

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Objectives

CHEM 104H is the second half of an Honors general chemistry sequence designed for students majoring in sciences other than chemistry. The goals of this sequence are: The CHEM 103-4H sequence deals with fewer topics, on a more conceptual basis, than the majors' chemistry courses; it differs from the regular CHEM 103-4 offering in its small class size, its strong emphasis on active, collaborative, and problem-based learning, and a more rigorous, process-oriented laboratory program.  CHEM 103H explored the connections among electronic configuration, bonding, molecular structure, and physical properties of an individual substance.  CHEM 104H now considers the interactions among different substances - i.e., the behavior of chemical systems. Topics considered include: the properties of solutions; the rates of chemical reactions; the nature of chemical equilibria, with an emphasis on acid-base systems; the roles of energy and entropy as driving forces in chemical systems; and electrochemistry.

 

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Professor 

Professor Susan E. Groh
  208 Brown Laboratory
  Phone: 831-2915 (office)
  E-mail: sgroh@udel.edu

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Office Hours

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Problem Session

An optional problem session is offered in this course. This is extra time set aside for those who would like to work on problem-solving skills, review old exam questions and answers, clarify topics discussed in class, discuss labwork, etc. in more detail than is usually possible during class. The session will run from 2-5 P.M. every Thursday in 212 Brown Lab, unless announced otherwise. The same subjects can, of course, also be addressed during office hours or by appointment, for those who can't make this session. I am always available for questions via e-mail as well.

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Class Meeting Time

Room 203, Brown Lab
  sec. 80: MWF 10:10 A.M. - 11:00 A.M.
  sec. 81: MWF 11:15 A.M - 12:05 P.M.
 
*Exam/Special Meeting Time
Thursday 6-9 P.M. on designated dates
 (see calendar).  
205 Brown Lab


Lab Meeting Time

Room 006, Drake Hall
  sec. 82: M  3:35 P.M. - 6:35 P.M.
  sec. 83: T  3:30 P.M. - 6:30 P.M.
  sec. 84: T  7:00 P.M. - 10:00 P.M.

sec. 85:  T 12:30 P.M. - 3:30 P.M.

* Exam/Special Meeting Time:  Both sections will meet together for common hour exams.  The Thursday night discussion time may also be used for review or other special sessions - these will be announced as needed.  Since this time slot has been blocked off on your schedules, please do not expect to take the exam at a different time because of a conflict with extracurricular (or irregular curricular) activities.  makeup exams are strongly discouraged, and are reserved for critical situations only.  There may be a take-home group component in some exams.

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Texts and Materials: (available at UD Bookstore)

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Grading

Grade Weighting Scheme Point Recapture Lab Grading Scheme

Final grades will be based on the following weighting scheme:
 
 

Hour Exams (3) 45%
Comprehensive Final Exam 15%
Problem Sets & Assignments 15%
Laboratory Reports 20%
Participation/Group Evaluations 5%

Educational research suggests that learning is enhanced in situations where students can cooperate, rather than compete, with one another. To encourage this, bell-curve grading is not used in this course; for you to succeed does not mean that someone else must fail. Rather, the absolute "mastery" grading standard indicated below will be used:
 

    45   49   54   58   62   67   71   75   80   84   88   100
 F  | D- || D+ | C- || C+ | B- || B+ | A- ||

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Point Recapture System.

(Modeled on an approach described by Dudley Herschbach in "Making Grading Less Painful", with M. Pickering, in Journal of College Science Teaching, vol. 21, pp.377-379, 1991.) Everyone has bad days now and again; unfortunately, sometimes they happen to fall on exam days. The point recapture system gives you a chance to make up for disastrous exams through an improved performance on the final exam. Most major concepts will be examined in both the hour and final exams; if you earn a higher percentage on a final exam question than you did on the corresponding hour exam question, the higher score is used to recalculate your hour exam grade. Thus, if you learn what you didn't know before, in time for the final, you not only eliminate your ignorance, but get credit for your effort - making us both happy.

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The Laboratory

The laboratory portion of this course provides the opportunity for "hands-on" explorations of a variety of chemical principles. The lab experiments have been chosen to complement and enrich (not duplicate) the expected course of activities in class; some labs will relate directly to topics fromclass, while others will illustrate further applications or related ideas. There will generally be some brief classroom discussion about each experiment, but you may find it useful to consult your textbook or other references for more background information about certain topics. Many standard chemical techniques and practices are outlined briefly in the Appendix to the lab manual.

Each laboratory session is overseen by a teaching assistant ("TA"); typically graduate students in chemistry, TA's are responsible for maintaining a safe lab environment, and for providing assistance and advice as you carry out the experiments. They also grade the lab reports, following the common grading schemes prepared and furnished by the course instructor; the instructor, however, has ultimate responsibility for the lab, and assigns the final lab grade. Questions about an experiment may be directed to Prof. Groh and/or the TA's.

More information about the lab, including a discussion of what's expected in a lab report, may be found in the Appendix to the lab manual.

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Lab Grading System.

One of the goals of the laboratory program is to expose you to the process of doing science. There is a myth about the scientific method (observation, hypothesis, experiment, analysis, and conclusion) that often is present in students' minds - namely, that these steps always proceed linearly and in sequence. In actuality real scientists occasionally stumble, collect data inaccurately, misinterpret or overinterpret results, miss significant aberrations, and so on. Science isn't a one-shot deal; one isn't always right or blessed with understanding at each and every stage. Chances are good that this will be your experience too, at times.

In order to minimize this problem, real-world science relies on the peer review system. When a scientist writes a paper describing some results, the paper is first submitted to other workers in that field for review. These reviewers look for problems in experimental design and execution, in data interpretation, and in analysis and extrapolation of results; if problems are found, the author is given the chance to correct them before the material is communicated to the rest of the scientific community.

We will utilize a similar system of evaluation in this course (based on an approach described by Miles Pickering in "Making Grading Less Painful", with D. Hershbach, in the Journal of College Science, vol 21, pp.377-379 (1991) ), teaching"with your lab teaching assistant serving as your initial peer reviewer. Lab reports will be graded according to the general guidelines below.  Each lab is nominally worth 100 points; of these, 5 points are reserved as "discretionary" points, to be awarded (in whole or part) by the lab TA as a measure of adequate completion of the prelab questions (before lab!) and of competent lab performance. Another 5 points will be assigned as a measure of accuracy in experimental results. The remainder of each lab report, then, may earn a maximum possible score of 90 points.  In conjunction with these 90 points, each lab report will receive one of the following ratings:

It is your decision as to whether or not to revise and resubmit a report. Any revised reports that become "Accepted" will be awarded 85 (out of 90) points for the written section. (The 5-point cost of revision is to discourage the initial submission of "rough draft" lab reports.) Revised reports that are still not completely acceptable will receive a grade no lower than the original. In this system, if you make mistakes in your first lab report, you still have the chance to learn from those mistakes and to regain almost full credit. The final lab grade will be an average over all the experiments, using the points indicated above.

Lab reports will generally be due one week after completion of the experimental work; revisions, within three days of receiving the graded lab. Makeup labs, due to the tight scheduling of 006 Drake, are not possible. If you can't make your usual lab section for a legitimate reason, you may be able to get into another section that week, depending on the availability of space: see me as soon as you recognize the conflict. Labs cannot be made up in subsequent weeks, and lab reports will be rejected if not received within the specified time; consult either the TA or Prof. Groh if an extension is needed.

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Class Format

"At times I felt the professor's notes became my notes without passing through either of our minds."

The traditional lecture approach to teaching is an excellent way to transfer information from one notebook to another; unfortunately, it's not necessarily an excellent way to develop a real understanding of chemistry. You don't learn how to ride a bike or speak French by listening to someone explain how to do it - you've got to try it yourself. To learn any subject well, including chemistry, you have to become actively involved in the learning process. The format of this course is designed to encourage that involvement by combining a problem-based, group-centered introduction to concepts with whole class discussions and mini-lectures. Participation is encouraged and expected in all these activities, as befits an Honors course (please note the 5% "participation" component of the course grade!). To repeat an old but nonetheless accurate adage, " the only stupid question is the one not asked" - if you have doubts about something, I can assure you that there will be others with the same question!

In problem-based learning, problems are used tointroduce various ideas or topics and to serve as focal points for learning new material; you may find this a bit unusual, if you're accustomed to only working on problems after all the pertinent material has already been thoroughly discussed in class. One purpose of this "problem-based learning" is to have the problem provide a context and reason for learning the material: you're not expected to be able to come up with a solution instantly - in fact, if you can, then I've written a poor problem! The problems are meant to encourage a dialogue within your group about what knowledge or insights each of you can bring to the situation, what information you collectively still lack, and where to find that information. Students in this course have a wide range of backgrounds and experiences in chemistry, but each can make a valuable contribution to the efforts of the group. Some students may have more "content" knowledge than others, and will be able to test just how deep that knowledge is, by trying to explain an idea to someone else. Others, by virtue of being unfamiliar with a particular area, can often help their group see a situation from different perspectives and, through their questions, make certain that all in the group end up really understanding the material.

In this course, at least in the early stages, the course text will generally be an adequate resource for the information or ideas you'll need to deal with problems; I will provide a collection of general chem texts for use in class, but you may prefer to have one person in your group bring along a copy of the course text, as well. You should be accustomed to viewing the whole text, not just the most pertinent chapter, as a source of information; in addition, the Chemistry library (located on the second floor of Brown Lab) has a wealth of reference materials, including several additional general chemistry texts that are placed on reserve for this course. The Internet is a good source as well, particularly for more topical information, provided that you take care to evaluate the reliability of any sites you consult. See http://www2.lib.udel.edu/usered/infolit/search.htm for helpful guidelines.

You are encouraged to work together in this course - not just on formal group assignments, but on other problem sets and lab reports as well. If you've collaborated with others in any way in preparing an individual assignment, you are responsible for (1) preparing your own answers in your own words , and (2) acknowledging your discussions with others by citing your collaborators' names in your assignment. Please note: (1) work that appears simply to have been copied from another's paper will not be accepted from either student involved; (2) work that has been copied from someone else (or carefully modified by changes in adjectives, voice, etc.) sticks out like a sore thumb - it is very easy to spot without trying, and it will be noticed.  Even when you have worked together with others, an answer constructed from your own understanding of the problem will sound different from anyone else's.  Copying is a violation of the academic code of conduct - don't do it.

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Assignments

In addition to lab reports and exams, several problem sets will be assigned during the course of the semester and collected for grading. There may be other sporadic assignments as well - for example, group or individual reports from your group's work on a problem, a short reflection paper on some material, etc.  Daily "homework" is not assigned in the class, but it is expected that your study routine for this course will include reading the text and working problems at the end of the chapters. The "section" problems, because they are often one-dimensional and fairly simple, are good for drills in learning the basics, but are not what you should expect to see on exams; do enough of these to feel comfortable with different types of calculations, then move on to the "Comprehensive" problems. The course packet contains a collection of old exams and problem sets which are invaluable study aids; you will find that such problems are a much better reflection of what you can expect to see on your own exams, than are most end-of-chapter exercises. In addition, the text on reserve by Brown, LeMay, and Burstyn has better-than-usual end-of-chapter exercises, and you might find it useful to challenge yourself with the "Additional Exercises" - a number of old exam questions have come from these pages.

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Group Work

In this class you will often be asked to work together in a group ( of about four students) on exercises or problems. Working in a group offers an excellent opportunity for you to brainstorm, discuss ideas, try out solutions, etc., in a nonthreatening atmosphere. A number of studies now confirm that students who work and study in groups generally come to a greater understanding of the material than those who work solely on their own; even students who initially feel that they will do better on their own, find that trying to explain something to someone else is an excellent way to test and reinforce that understanding. In addition, group work can be a lot more fun, and in the process you develop the interpersonal skills and practice in teamwork that future employers find very valuable.  (Please see the "Working in Groups" FAQ at http://www.udel.edu/pbl/working-in-groups/ for more discussion.)

During an assignment each person in the group is expected to participate fully; to ensure that, each member will be assigned a role to fulfill. These roles will rotate with each assignment or activity. The descriptions of responsibility for each of these roles follows:

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Ground rules

While it's to be understood that students will treat one another with the concern and respect that they would wish for themselves, it is also important to establish ground rules and consequences for behavior when working in groups. Each group will decide on the groundrules they will adopt; the following is a recommended minimal list, with the first two being mandatory:
  1. Attendance is mandatory - if you are absent, you are hurting your group. Problems are designed to draw on the strengths of all four members, with a role assigned to each. If you do not attend, there is a gap in responsibility.
  2. Come to class prepared. It is your responsibility to be ready to contribute to the group effort.
  3. Fulfill the responsibility of your role. If you are the reporter, you must prepare and turn in the assignment. If you are the resource person/advocate, you must bring the text and notes, and probe your classmates' understanding, etc.
  4. If there is disagreement about problem-solving strategies, solutions, conclusions, etc., the group should come to consensus before writing up the assignment. However, if the group agrees, a "minority" report can be submitted with the group assignment.
  5. The groups agrees not to ignore infractions of the ground rules or the attendant consequences.
Your group can establish other ground rules as long as everyone in the group is in consensus. Your group should also discuss consequences: i.e., how you want to deal with group members who do not carry their share of the responsibility. Please note that you will be given the opportunity to evaluate the contributions of each member of the group (including yourself) to the group's progress; these comments, together with the instructor's observations, will be used in evaluating the "participation/group evaluation" component of the course grade.   If a problem should arise in your group, turning to the group's ground rules and consequences is the first step in resolving the conflict.  If requested, the course instructor can serve as a mediator if the conflict persists.  If these steps fail, the instructor has the final decision on grades, and reserves teh right to apply penalties for nonparticipation, poor group performance, etc. as appropriate. 

Make sure all members of the group have a copy of the groundrules, and provide a set for the instructor as well. Each group should pick a "name" for itself, for ease of reference in class discussions; provide this on the list of groundrules. Be sure to share phone numbers and addresses for contacting one another; while most group work will be done in class, there will be occasions where you need to meet outside of class. 

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Other Policies

Attendance. Attendance in this class is mandatory since the group activities rely on every member being present. If you find you need to be absent for any reason, you must notify the other members of your group. It will also be necessary for you to contact them after the missed class to find out your assignments for any project that might have been initiated during that class.

Safety. Delaware state law requires that you wear safety goggles AT ALL TIMES when working in a chemical laboratory - from the moment you enter until the time you leave, unless the TA explicitly states that goggles are not needed that day. Any student not wearing goggles when required will be asked to leave the lab, and will receive a nonnegotiable grade of zero for that experiment. Safety rules also forbid the wearing of shorts, short skirts, or sandals in the lab; long or unruly hair must be restrained. You'll receive additional instructions concerning laboratory safety at your first lab meeting.

Integrity.  Academic dishonesty has no place in this or any other course. Cheating in any form (plagiarism, copying, altering information, , using cribs on exams, etc.) will result in judicial proceedings in accordance with the University's policy on academic dishonesty. For a discussion of what constitutes academic dishonesty, please see the Code of Conduct (online at http://www.udel.edu/stuguide/03-04/code.html#honesty ).

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How To Do Well in CHEM 104H

A standard rule of thumb for most college courses is that you should expect to spend 2-3 hours in study for every hour spent in class. This course is no exception - developing more than a superficial understanding of chemistry takes effort, and effort requires time.  If you need help with time management skills, contact the Academic Services Center ; they offer sessions on time management, note-taking and reading strategies that you might find useful.  

Here are some other recommendations, from former students:

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Course Outline

Exam Schedule Problem Set Schedule

Schedule of Topics and Readings
 

Dates (approx.) Topics Readings
2/11-2/25 Solutions Ch. 13
2/27-3/12 Chemical Kinetics Ch. 16
3/12-3/17, 3/29-4/2   Chemical Equilibria Ch. 17
3/22-3/26 SPRING BREAK

4/5-4/12 Chemistry of Acids and Bases Ch. 18
4/14-4/28 Reactions between Acids and Bases
(titrations, buffers)
Ch. 19
4/30-5/3 Precipitation Reactions Ch. 19
5/5-5/10 Entropy and Free Energy Ch. 20
5/12-5/19 Electrochemistry Ch. 21

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Exam Schedule

Mar. 11 EXAM 1 205 Brown Lab 6:00 - 9:00  P.M.
Apr. 15 EXAM 2 205 Brown Lab 6:00 - 9:00  P.M.
May 13 EXAM 3 205 Brown Lab 6:00 - 9:00  P.M.

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Problem Set Schedule

Anticipated schedule for problem set assignments:
 

Problem Set
Handed Out
Due Date
1
2/27
3/5
2
4/2
4/9
3
4/30
5/7

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Other important dates:
 

Feb. 23 End of free drop/add period
Mar. 22-26 Spring Break: no classes
Mar. 26
First year students' midterm marking period ends
Apr. 9 Last day to change registration or withdraw from courses w/o academic penalty
May 7 Honors Day
May 19 Last day of classes
May 21-28 Final exam period

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Laboratory Schedule

Date Experiment Lab Report Due For
2/16-17 Safety; Determination of a Critical Micelle Concentration
2/23-24 Kinetics of Dye Decolorization CMC expt.
3/1-2 Kinetics cont'd.
3/8-9 Identification of an Unknown Cation (plots of Trials 1-4)
3/15-16 Identification cont'd. Full kinetics expt.
3/22-23 Spring Break: No Labs
3/29-30 Determination of an Equilibrium Constant
Unknown cation expt.
4/5-6 TBA
Eq  constant expt.
4/12-13 Acid-Base Titration Curves 

Also: Prepare iron oxalate for "Synthesis" expt.


4/19-20 Buffer Solutions 

Also: Collect crystals from last week's prep


4/26-27 Synthesis of an Iron Coordination Complex A-B Titration expt.
5/3-4 Synthesis cont'd. Buffer expt.
5/12

Synthesis (due in class)

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"http://www.udel.edu/~sgroh/chem104syll.html" 
Last updated February 2, 2004. 
Copyright Susan Groh, Univ. of Delaware, 1997.